Fischer-tropsch synthesis over zeolite-supported ruthenium catalysts derived from Ru3(CO)12

Y. W. Chen; H. T. Wang; J. G. Goodwin; W. K. Shiflett

doi:10.1016/0166-9834(83)85001-5

Fischer-tropsch synthesis over zeolite-supported ruthenium catalysts derived from Ru₃(CO)₁₂

Y. W. Chen, H. T. Wang, J. G. Goodwin, W. K. Shiflett

Department of Chemical and Materials Engineering

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

A set of zeolite-supported Ru catalysts was prepared from Ru₃(CO)₁₂ using zeolites NaX, NaY, KL and NaMordenite. These catalysts were characterized and studied under Fischer-Tropsch conditions in order to determine their unique properties and the effect of the zeolite support. For comparison, a catalyst using SiO₂ as support was also used. Ru₃(CO)₁₂ did not appear to be able to diffuse into NaX. Overall, the best catalyst in terms of high Ru dispersion, low methane selectivity and high olefin selectivity was Ru/NaY. The type of zeolite used as the support had a strong effect on methane selectivity. This method of preparation, compared to the ion-exchange method, is much superior in producing low yields of methane and high yields of olefins.

Original language	English
Pages (from-to)	303-314
Number of pages	12
Journal	Applied Catalysis
Volume	8
Issue number	3
DOIs	https://doi.org/10.1016/0166-9834(83)85001-5
State	Published - 15 Dec 1983

Access to Document

10.1016/0166-9834(83)85001-5

Cite this

@article{fdb803c79c794933bc3eb8c019528dbe,

title = "Fischer-tropsch synthesis over zeolite-supported ruthenium catalysts derived from Ru3(CO)12",

abstract = "A set of zeolite-supported Ru catalysts was prepared from Ru3(CO)12 using zeolites NaX, NaY, KL and NaMordenite. These catalysts were characterized and studied under Fischer-Tropsch conditions in order to determine their unique properties and the effect of the zeolite support. For comparison, a catalyst using SiO2 as support was also used. Ru3(CO)12 did not appear to be able to diffuse into NaX. Overall, the best catalyst in terms of high Ru dispersion, low methane selectivity and high olefin selectivity was Ru/NaY. The type of zeolite used as the support had a strong effect on methane selectivity. This method of preparation, compared to the ion-exchange method, is much superior in producing low yields of methane and high yields of olefins.",

author = "Chen, {Y. W.} and Wang, {H. T.} and Goodwin, {J. G.} and Shiflett, {W. K.}",

note = "Funding Information: Support for this work was provided by the Department of Energy under Grant",

year = "1983",

month = dec,

day = "15",

doi = "10.1016/0166-9834(83)85001-5",

language = "???core.languages.en_GB???",

volume = "8",

pages = "303--314",

journal = "Applied Catalysis",

issn = "0166-9834",

number = "3",

}

TY - JOUR

T1 - Fischer-tropsch synthesis over zeolite-supported ruthenium catalysts derived from Ru3(CO)12

AU - Chen, Y. W.

AU - Wang, H. T.

AU - Goodwin, J. G.

AU - Shiflett, W. K.

N1 - Funding Information: Support for this work was provided by the Department of Energy under Grant

PY - 1983/12/15

Y1 - 1983/12/15

N2 - A set of zeolite-supported Ru catalysts was prepared from Ru3(CO)12 using zeolites NaX, NaY, KL and NaMordenite. These catalysts were characterized and studied under Fischer-Tropsch conditions in order to determine their unique properties and the effect of the zeolite support. For comparison, a catalyst using SiO2 as support was also used. Ru3(CO)12 did not appear to be able to diffuse into NaX. Overall, the best catalyst in terms of high Ru dispersion, low methane selectivity and high olefin selectivity was Ru/NaY. The type of zeolite used as the support had a strong effect on methane selectivity. This method of preparation, compared to the ion-exchange method, is much superior in producing low yields of methane and high yields of olefins.

AB - A set of zeolite-supported Ru catalysts was prepared from Ru3(CO)12 using zeolites NaX, NaY, KL and NaMordenite. These catalysts were characterized and studied under Fischer-Tropsch conditions in order to determine their unique properties and the effect of the zeolite support. For comparison, a catalyst using SiO2 as support was also used. Ru3(CO)12 did not appear to be able to diffuse into NaX. Overall, the best catalyst in terms of high Ru dispersion, low methane selectivity and high olefin selectivity was Ru/NaY. The type of zeolite used as the support had a strong effect on methane selectivity. This method of preparation, compared to the ion-exchange method, is much superior in producing low yields of methane and high yields of olefins.

UR - http://www.scopus.com/inward/record.url?scp=0020945696&partnerID=8YFLogxK

U2 - 10.1016/0166-9834(83)85001-5

DO - 10.1016/0166-9834(83)85001-5

M3 - 期刊論文

AN - SCOPUS:0020945696

SN - 0166-9834

VL - 8

SP - 303

EP - 314

JO - Applied Catalysis

JF - Applied Catalysis

IS - 3

ER -

Fischer-tropsch synthesis over zeolite-supported ruthenium catalysts derived from Ru3(CO)12

Abstract

Access to Document

Fingerprint

Cite this

Fischer-tropsch synthesis over zeolite-supported ruthenium catalysts derived from Ru₃(CO)₁₂