Experimental study of the DCCI X̃1 A′ state vibrational structure by dispersed fluorescence spectroscopy

Chia Ling Lee, Mei Lung Liu, Bor Chen Chang

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

The LIF excitation spectra of several DCCI Ã-X̃ vibronic transitions between 570 and 620 nm using a combination of direct current discharge and supersonic free jet expansion techniques were successfully recorded and a total of three vibronic bands as observed. Dispersed fluorescence spectra following pumping of the DCCl à state (0,6,0), (0,7,0), and (0,8,0) levels were obtained for the first time. This paper provides good experimental data for refining calculations on potential energy surfaces.

Original languageEnglish
Pages (from-to)3263-3268
Number of pages6
JournalJournal of Chemical Physics
Volume117
Issue number7
DOIs
StatePublished - 15 Aug 2002

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