Effects of surfactant micelles on viscosity and conductivity of poly(ethylene glycol) solutions

Shun Cheng Wang, Tzu Chien Wei, Wun Bin Chen, Heng Kwong Tsao

Research output: Contribution to journalArticlepeer-review

49 Scopus citations

Abstract

The polymer-micelle interaction was investigated for various surfactants using viscometry and electric conductometry. The interaction was analyzed by examining the change in the transport properties and the change in the onset point of the thermodynamic instability for an aqueous mixture of polymer and surfactant. It was found that addition of a particular surfactant results in significant viscosity increment of the polymer solution and addition to the polymers lowers the onset point of self-assembly associated with the dilute surfactant solution. The rapid growth of the viscosity with surfactant concentration was related to the formation of cross links among micelles and polymers.

Original languageEnglish
Pages (from-to)4980-4988
Number of pages9
JournalJournal of Chemical Physics
Volume120
Issue number10
DOIs
StatePublished - 8 Mar 2004

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