Effect of the interfacial transition zone on the migration behavior of cations under the Accelerated Lithium Migration Technique

Chih Chien Liu, Wei Chien Wang

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

This paper researches the effect of the interfacial transition zone (ITZ) on the migration behavior of cations under the Accelerated Lithium Migration Technique (ALMT). Cylindrical mortars with different aggregate volume fractions (Vf) and w/c=0.5 were used. The result shows that when Vf ≤ 20 %, the Li+ steady state migration coefficient (Ds) is influenced by the dilution and tortuosity effects of the aggregate. The combined effect of ITZ and percolation occurs at Vf = 30 %, and the effects increase with the increase in Vf. Based on the experimental and regression analysis results, when the assumed thickness of ITZ = 20 μm, the approximate Ds of ITZ and percolated ITZ are 46.4 and 52.6 times the matrix migration coefficient.

Original languageEnglish
Title of host publicationAdvanced Building Materials
Pages3743-3747
Number of pages5
DOIs
StatePublished - 2011
Event1st International Conference on Civil Engineering, Architecture and Building Materials, CEABM 2011 - Haikou, China
Duration: 18 Jun 201120 Jun 2011

Publication series

NameAdvanced Materials Research
Volume250-253
ISSN (Print)1022-6680

Conference

Conference1st International Conference on Civil Engineering, Architecture and Building Materials, CEABM 2011
Country/TerritoryChina
CityHaikou
Period18/06/1120/06/11

Keywords

  • Diffusion
  • Electrochemical techniques
  • Interfacial transition zone
  • Migration

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