Effect of restrictive diffusion on hydrodesulfurization of heavy residue oils over CoMo/Al2O3

Yu‐Wen ‐W Chen, Ming‐Chang ‐C Tsai, Chiuping Li, Ben‐Chang ‐C Kang

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8 Scopus citations

Abstract

The effect of the ratio of reactant molecular diameter to catalyst pore diameter (λ) on the restrictive diffusion under hydrodesulfurization (HDS) reactions of heavy residue oils over CoMo/Al2O3 catalysts was investigated. A series of Al2O3 with various pore structures were used as supports of CoMo sulfide. The HDS reaction was carried out in a semi‐batch Carberry type reactor at 648 K and 10.3 MPa. Two empirical correlations for restrictive diffusion under HDS reaction conditions were developed depending on the value of λ. The results showed that the restrictive diffusion effect under HDS reaction conditions is severe for the lower values of λ. However, this effect seems not prominent for higher values of λ. The order of the magnitude of the effective diffusivity was in the range of 10−6‐10−7 cm2/s for the sulfur‐containing compounds of residue oil in CoMo/Al2O3 catalysts at 648 K.

Original languageEnglish
Pages (from-to)854-861
Number of pages8
JournalThe Canadian Journal of Chemical Engineering
Volume72
Issue number5
DOIs
StatePublished - Oct 1994

Keywords

  • CoMo/AlO
  • hydrodesulfurization
  • restrictive diffusion

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