Effect of nitric acid oxidation on the surface of hydrochars to sorb methylene blue: An adsorption mechanism comparison

Duy H. Nguyen, Hai Nguyen Tran, Huan Ping Chao, Chu Ching Lin

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25 Scopus citations


The capacity and underlying mechanism of hydrochars derived from commercial D-glucose and wasted orange peels (designated as pristine-hydrochars) and further modified with nitric acid (designated as oxidized-hydrochars) to adsorb methylene blue were investigated. Both pristine- and oxidized-hydrochars were characterized by scanning electron microscopy, Brunauer–Emmet–Teller-specific surface area, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and mass titration. The maximum methylene blue adsorption capacity at 30°C estimated by the Langmuir model was found to follow the order: mGH (246 mg/g) > mOPH (107 mg/g) > OPH (59.6 mg/g) > GH (54.8 mg/g). Six adsorption mechanisms were elucidated, in which the electrostatic interaction and hydrogen bonding were identified as the primary methylene blue-hydrochar adsorptive interaction; furthermore, because the nitric acid modification process enhanced oxygen- and nitrogen-containing functional groups and unsaturated bonds on the surface of oxidized-hydrochars, the π–π and n–π interaction became minor pathways for methylene blue adsorption onto oxidized-hydrochars. Our results suggest that modified hydrochars could be used as environmentally friendly adsorbents alternative to activated carbon in dealing with methylene blue contamination in aqueous solutions.

Original languageEnglish
Pages (from-to)607-622
Number of pages16
JournalAdsorption Science and Technology
Issue number7-8
StatePublished - 1 Oct 2019


  • adsorption mechanisms
  • environmentally friendly adsorbents
  • methylene blue
  • Oxidized-hydrochars
  • oxygenated functional groups


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