Directed ortho insertion (Dol): A new approach to functionalized aryl and heteroaryl zinc reagents

Nadège Boudet; Shohei Sase; Pradipta Sinha; Ching Yuan Liu; Arkady Krasovskiy; Paul Knöchel

doi:10.1021/ja074060h

Directed ortho insertion (Dol): A new approach to functionalized aryl and heteroaryl zinc reagents

Nadège Boudet, Shohei Sase, Pradipta Sinha, Ching Yuan Liu, Arkady Krasovskiy, Paul Knöchel

Department of Chemical and Materials Engineering

Research output: Contribution to journal › Article › peer-review

81 Scopus citations

Abstract

A wide range of directing groups (ester, ketone, acetate, aryl sulfonate, triazene, carbamate) allow the regioselective directed ortho insertion (DoI) of zinc in the presence of LiCl leading to polyfunctional aryl and heteroaryl zinc reagents.

Original language	English
Pages (from-to)	12358-12359
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	41
DOIs	https://doi.org/10.1021/ja074060h
State	Published - 17 Oct 2007

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title = "Directed ortho insertion (Dol): A new approach to functionalized aryl and heteroaryl zinc reagents",

abstract = "A wide range of directing groups (ester, ketone, acetate, aryl sulfonate, triazene, carbamate) allow the regioselective directed ortho insertion (DoI) of zinc in the presence of LiCl leading to polyfunctional aryl and heteroaryl zinc reagents.",

author = "Nad{\`e}ge Boudet and Shohei Sase and Pradipta Sinha and Liu, {Ching Yuan} and Arkady Krasovskiy and Paul Kn{\"o}chel",

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T2 - A new approach to functionalized aryl and heteroaryl zinc reagents

AU - Boudet, Nadège

AU - Sase, Shohei

AU - Sinha, Pradipta

AU - Liu, Ching Yuan

AU - Krasovskiy, Arkady

AU - Knöchel, Paul

PY - 2007/10/17

Y1 - 2007/10/17

N2 - A wide range of directing groups (ester, ketone, acetate, aryl sulfonate, triazene, carbamate) allow the regioselective directed ortho insertion (DoI) of zinc in the presence of LiCl leading to polyfunctional aryl and heteroaryl zinc reagents.

AB - A wide range of directing groups (ester, ketone, acetate, aryl sulfonate, triazene, carbamate) allow the regioselective directed ortho insertion (DoI) of zinc in the presence of LiCl leading to polyfunctional aryl and heteroaryl zinc reagents.

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U2 - 10.1021/ja074060h

DO - 10.1021/ja074060h

M3 - 期刊論文

C2 - 17887673

AN - SCOPUS:35348943330

SN - 0002-7863

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SP - 12358

EP - 12359

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 41

ER -

Directed ortho insertion (Dol): A new approach to functionalized aryl and heteroaryl zinc reagents

Abstract

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