Cs8UIV(UVIO2) 3(Ge3O9)3·3H2O: A mixed-valence uranium germanate with 9-ring channels

Quang Bac Nguyen, Hsin Kuan Liu, Wen Jung Chang, Kwang Hwa Lii

Research output: Contribution to journalArticlepeer-review

31 Scopus citations

Abstract

A mixed-valence uranium(IV,VI) germanate has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains discrete UIVO6 octahedra and UVIO6 tetragonal bipyramids, which are connected by three-membered single-ring Ge 3O96- anions to form a three-dimensional framework with 9-ring channels. The U 4f X-ray photoelectron spectroscopy spectrum was measured to identify the valence states of the uranium.

Original languageEnglish
Pages (from-to)4241-4243
Number of pages3
JournalInorganic Chemistry
Volume50
Issue number10
DOIs
StatePublished - 16 May 2011

Fingerprint

Dive into the research topics of 'Cs8UIV(UVIO2) 3(Ge3O9)3·3H2O: A mixed-valence uranium germanate with 9-ring channels'. Together they form a unique fingerprint.

Cite this