Abstract
A mixed-valence uranium(IV,VI) germanate has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains discrete UIVO6 octahedra and UVIO6 tetragonal bipyramids, which are connected by three-membered single-ring Ge 3O96- anions to form a three-dimensional framework with 9-ring channels. The U 4f X-ray photoelectron spectroscopy spectrum was measured to identify the valence states of the uranium.
Original language | English |
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Pages (from-to) | 4241-4243 |
Number of pages | 3 |
Journal | Inorganic Chemistry |
Volume | 50 |
Issue number | 10 |
DOIs | |
State | Published - 16 May 2011 |
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CSD 1783182: Experimental Crystal Structure Determination
Liu, H. (Contributor), Chang, W. (Contributor), Lii, K. (Contributor) & Nguyen, Q. B. (Contributor), The Cambridge Structural Database, 1 Jan 2011
DOI: 10.25505/fiz.icsd.cc1xvk0b, https://doi.org/10.25505%2Ffiz.icsd.cc1xvk0b
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