A mixed-valence uranium(IV,VI) germanate has been synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains discrete UIVO6 octahedra and UVIO6 tetragonal bipyramids, which are connected by three-membered single-ring Ge 3O96- anions to form a three-dimensional framework with 9-ring channels. The U 4f X-ray photoelectron spectroscopy spectrum was measured to identify the valence states of the uranium.
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Liu, H. (Contributor), Chang, W. (Contributor), Lii, K. (Contributor) & Nguyen, Q. B. (Contributor), The Cambridge Structural Database, 1 Jan 2011