Cs2K(UO)2Si4O12: A mixed-valence uranium(IV,V) silicate

Cheng Shiuan Lee, Sue Lein Wang, Kwang Hwa Lii

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Abstract

(Chemical Equation Presented) The first mixed-valence uranium(IV,V) silicate is synthesized under high-temperature, high-pressure hydrothermal conditions. The structure contains chains of corner-sharing U IV,VO6 octahedra which are interconnected by Si 4O12 four-membered rings to form a 3-D framework. XPS and XANES spectra were measured to identify the valence state of uranium.

Original languageEnglish
Pages (from-to)15116-15117
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number42
DOIs
StatePublished - 28 Oct 2009

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