Complex Magnetic Phases in Nanosized Core@Shell Prussian Blue Analogue Cubes: Rb0.48Co[Fe(CN)6]0.75[(H2O)6]0.25·0.34H2O@K0.36Ni[Cr(CN)6]0.74[(H2O)6]0.26·0.11H2O

Chi Hung Lee; Chun Ming Wu; Erdembayalag Batsaikhan; Hsiao Chi Li; Carissa H. Li; Marcus K. Peprah; Daniel R. Talham; Mark W. Meisel; Wen Hsien Li

doi:10.1021/acs.jpcc.5b07274

Complex Magnetic Phases in Nanosized Core@Shell Prussian Blue Analogue Cubes: Rb_0.48Co[Fe(CN)₆]_0.75[(H₂O)₆]_0.25·0.34H₂O@K_0.36Ni[Cr(CN)₆]_0.74[(H₂O)₆]_0.26·0.11H₂O

Chi Hung Lee, Chun Ming Wu, Erdembayalag Batsaikhan, Hsiao Chi Li, Carissa H. Li, Marcus K. Peprah, Daniel R. Talham, Mark W. Meisel, Wen Hsien Li

Department of Physics

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Different magnetic phases have been identified in nanosized core/shell Prussian blue analogue (PBA) cubes, with a 250 nm Rb-Co-Fe phase (Rb_0.48Co[Fe(CN)₆]_0.75[(H₂O)₆]_0.25·0.34H₂O) in the core coated by a 45 nm K-Ni-Cr phase (K_0.36Ni[Cr(CN)₆]_0.74[(H₂O)₆]_0.26·0.11H₂O) on the shell. Three separate characteristic temperatures at 86, 69, and 67 K are associated with magnetic phases in the K-Ni-Cr shell. Two magnetic exchange paths are identified. One propagates along the three crystallographic axis directions. The other propagates along the [110] crystallographic direction for the associated Ni-Ni interactions, but not for Cr-Cr interactions. The severe Cr deficiency and the appearance of direct Ni-Ni exchange are used to understand the appearance of two separate transitions associated with magnetic ordering. A weak moment develops in the core at low temperature, corresponding to separate ordering of the Co-Fe PBA network.

Original language	English
Pages (from-to)	29138-29147
Number of pages	10
Journal	Journal of Physical Chemistry C
Volume	119
Issue number	52
DOIs	https://doi.org/10.1021/acs.jpcc.5b07274
State	Published - 31 Dec 2015

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10.1021/acs.jpcc.5b07274

Interplay between Electrical Conduction and Ferromagnetism in New Nano-Sized or Novel Material(1/3)
Li, W.-H. (PI)
1/08/15 → 31/07/16
Project: Research

Cite this

Lee, C. H., Wu, C. M., Batsaikhan, E., Li, H. C., Li, C. H., Peprah, M. K., Talham, D. R., Meisel, M. W., & Li, W. H. (2015). Complex Magnetic Phases in Nanosized Core@Shell Prussian Blue Analogue Cubes: Rb_0.48Co[Fe(CN)₆]_0.75[(H₂O)₆]_0.25·0.34H₂O@K_0.36Ni[Cr(CN)₆]_0.74[(H₂O)₆]_0.26·0.11H₂O. Journal of Physical Chemistry C, 119(52), 29138-29147. https://doi.org/10.1021/acs.jpcc.5b07274

@article{fd62ad2ac38c424e86091e2eba75309b,

title = "Complex Magnetic Phases in Nanosized Core@Shell Prussian Blue Analogue Cubes: Rb0.48Co[Fe(CN)6]0.75[(H2O)6]0.25·[email protected][Cr(CN)6]0.74[(H2O)6]0.26·0.11H2O",

abstract = "Different magnetic phases have been identified in nanosized core/shell Prussian blue analogue (PBA) cubes, with a 250 nm Rb-Co-Fe phase (Rb0.48Co[Fe(CN)6]0.75[(H2O)6]0.25·0.34H2O) in the core coated by a 45 nm K-Ni-Cr phase (K0.36Ni[Cr(CN)6]0.74[(H2O)6]0.26·0.11H2O) on the shell. Three separate characteristic temperatures at 86, 69, and 67 K are associated with magnetic phases in the K-Ni-Cr shell. Two magnetic exchange paths are identified. One propagates along the three crystallographic axis directions. The other propagates along the [110] crystallographic direction for the associated Ni-Ni interactions, but not for Cr-Cr interactions. The severe Cr deficiency and the appearance of direct Ni-Ni exchange are used to understand the appearance of two separate transitions associated with magnetic ordering. A weak moment develops in the core at low temperature, corresponding to separate ordering of the Co-Fe PBA network.",

author = "Lee, {Chi Hung} and Wu, {Chun Ming} and Erdembayalag Batsaikhan and Li, {Hsiao Chi} and Li, {Carissa H.} and Peprah, {Marcus K.} and Talham, {Daniel R.} and Meisel, {Mark W.} and Li, {Wen Hsien}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = dec,

day = "31",

doi = "10.1021/acs.jpcc.5b07274",

language = "???core.languages.en_GB???",

volume = "119",

pages = "29138--29147",

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Lee, CH, Wu, CM, Batsaikhan, E, Li, HC, Li, CH, Peprah, MK, Talham, DR, Meisel, MW & Li, WH 2015, 'Complex Magnetic Phases in Nanosized Core@Shell Prussian Blue Analogue Cubes: Rb_0.48Co[Fe(CN)₆]_0.75[(H₂O)₆]_0.25·0.34H₂O@K_0.36Ni[Cr(CN)₆]_0.74[(H₂O)₆]_0.26·0.11H₂O', Journal of Physical Chemistry C, vol. 119, no. 52, pp. 29138-29147. https://doi.org/10.1021/acs.jpcc.5b07274

Complex Magnetic Phases in Nanosized Core@Shell Prussian Blue Analogue Cubes: Rb_0.48Co[Fe(CN)₆]_0.75[(H₂O)₆]_0.25·0.34H₂O@K_0.36Ni[Cr(CN)₆]_0.74[(H₂O)₆]_0.26·0.11H₂O. / Lee, Chi Hung; Wu, Chun Ming; Batsaikhan, Erdembayalag et al.
In: Journal of Physical Chemistry C, Vol. 119, No. 52, 31.12.2015, p. 29138-29147.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Complex Magnetic Phases in Nanosized Core@Shell Prussian Blue Analogue Cubes

T2 - Rb0.48Co[Fe(CN)6]0.75[(H2O)6]0.25·[email protected][Cr(CN)6]0.74[(H2O)6]0.26·0.11H2O

AU - Lee, Chi Hung

AU - Wu, Chun Ming

AU - Batsaikhan, Erdembayalag

AU - Li, Hsiao Chi

AU - Li, Carissa H.

AU - Peprah, Marcus K.

AU - Talham, Daniel R.

AU - Meisel, Mark W.

AU - Li, Wen Hsien

PY - 2015/12/31

Y1 - 2015/12/31

N2 - Different magnetic phases have been identified in nanosized core/shell Prussian blue analogue (PBA) cubes, with a 250 nm Rb-Co-Fe phase (Rb0.48Co[Fe(CN)6]0.75[(H2O)6]0.25·0.34H2O) in the core coated by a 45 nm K-Ni-Cr phase (K0.36Ni[Cr(CN)6]0.74[(H2O)6]0.26·0.11H2O) on the shell. Three separate characteristic temperatures at 86, 69, and 67 K are associated with magnetic phases in the K-Ni-Cr shell. Two magnetic exchange paths are identified. One propagates along the three crystallographic axis directions. The other propagates along the [110] crystallographic direction for the associated Ni-Ni interactions, but not for Cr-Cr interactions. The severe Cr deficiency and the appearance of direct Ni-Ni exchange are used to understand the appearance of two separate transitions associated with magnetic ordering. A weak moment develops in the core at low temperature, corresponding to separate ordering of the Co-Fe PBA network.

AB - Different magnetic phases have been identified in nanosized core/shell Prussian blue analogue (PBA) cubes, with a 250 nm Rb-Co-Fe phase (Rb0.48Co[Fe(CN)6]0.75[(H2O)6]0.25·0.34H2O) in the core coated by a 45 nm K-Ni-Cr phase (K0.36Ni[Cr(CN)6]0.74[(H2O)6]0.26·0.11H2O) on the shell. Three separate characteristic temperatures at 86, 69, and 67 K are associated with magnetic phases in the K-Ni-Cr shell. Two magnetic exchange paths are identified. One propagates along the three crystallographic axis directions. The other propagates along the [110] crystallographic direction for the associated Ni-Ni interactions, but not for Cr-Cr interactions. The severe Cr deficiency and the appearance of direct Ni-Ni exchange are used to understand the appearance of two separate transitions associated with magnetic ordering. A weak moment develops in the core at low temperature, corresponding to separate ordering of the Co-Fe PBA network.

UR - http://www.scopus.com/inward/record.url?scp=84953283201&partnerID=8YFLogxK

U2 - 10.1021/acs.jpcc.5b07274

DO - 10.1021/acs.jpcc.5b07274

M3 - 期刊論文

AN - SCOPUS:84953283201

SN - 1932-7447

VL - 119

SP - 29138

EP - 29147

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 52

ER -

Complex Magnetic Phases in Nanosized Core@Shell Prussian Blue Analogue Cubes: Rb0.48Co[Fe(CN)6]0.75[(H2O)6]0.25·0.34H2O@K0.36Ni[Cr(CN)6]0.74[(H2O)6]0.26·0.11H2O

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Interplay between Electrical Conduction and Ferromagnetism in New Nano-Sized or Novel Material(1/3)

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Complex Magnetic Phases in Nanosized Core@Shell Prussian Blue Analogue Cubes: Rb_0.48Co[Fe(CN)₆]_0.75[(H₂O)₆]_0.25·0.34H₂O@K_0.36Ni[Cr(CN)₆]_0.74[(H₂O)₆]_0.26·0.11H₂O