Catalytic decomposition of gaseous PCDD/Fs over V2O5/TiO2-CNTs catalyst: Effect of NO and NH3 addition

Qiulin Wang, Pao Chang Hung, Shengyong Lu, Moo Been Chang

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29 Scopus citations

Abstract

There is a strong need for a control technology that simultaneously achieving the abatement of PCDD/Fs (polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans) and nitrogen oxides (NOx) emissions in waste incineration industry. TiO2 and carbon nanotubes (CNTs) were used as composite carriers to support vanadium oxide as an innovative catalyst to simultaneously control PCDD/Fs and NO emissions. The removal efficiencies (RE) of PCDD/Fs by V2O5/TiO2-CNTs catalyst under a space velocity (SV) of 20,000 h−1 reaches 99.9% at 150 °C and adsorption is supposed to be the main mechanism at this temperature. The influence of [Formula presented]3 reaction on PCDD/Fs catalytic reaction is investigated. The kinetics analysis exhibits that the addition of NO and NH3 reduces the activation energies for OCDD (octachlorodibenzo-p-dioxin) and OCDF (octachlorodibenzofuran) decomposition to 3.6 kJ/mol and 5.4 kJ/mol respectively.

Original languageEnglish
Pages (from-to)132-137
Number of pages6
JournalChemosphere
Volume159
DOIs
StatePublished - 1 Sep 2016

Keywords

  • Carbon nanotubes
  • Catalytic decomposition
  • NO
  • PCDD/Fs
  • Simultaneous control

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