Calamitic metallomesogens derived from unsymmetric pyrazoles

Min Chou Chen, Shih Chieh Lee, Chia Chung Ho, Tarng Shiang Hu, Gene Hsiang Lee, Chung K. Lai

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12 Scopus citations


Three series of copper(II) complexes 1a-1c derived from unsymmetric pyrazoles 2a-2c were prepared and their mesomorphic properties investigated. The mesomorphic behavior of compounds was studied by differential scanning calorimetry, polarizing optical microscopy, and powder X-ray diffractometry. The crystal and molecular structures of mesogenic copper complex (2a; n=10) of 3-[4-decyloxyphenyl]-1H-pyrazole were determined by means of X-ray structural analysis. It crystallizes in the triclinic space group P-1, with a=4.0890(1) Å, b=18.0167(2) Å, c=25.5015(5) Å, and Z=2. The geometry at copper center was not perfectly square planar. A weak intermolecular H-bond (d=2.36 Å) between Cl1 and H2 atoms and π-π interaction (ca. 3.45-3.55 Å) was also observed. All their precursors 2a-2c were not mesogenic. In contrast, copper complexes 1a formed nematic or smectic C phases and complexes 1b-1c formed crystalline phases. Powder X-ray diffraction experiments confirmed the presence of SmC phase.

Original languageEnglish
Pages (from-to)9460-9467
Number of pages8
Issue number45
StatePublished - 7 Nov 2009


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