Anti-addition of Dimethylsulfoxonium Methylide to Acyclic α,β-Unsaturated Ketones and Its Application in Formal Synthesis of an Eicosanoid

Keyphrases

• Unsaturated Ketones 100%
• Formal Synthesis 100%
• Anti-addition 100%
• Dimethylsulfoxonium Methylide 100%
• Eicosanoids 100%
• Propylene 50%
• Tert 50%
• Spectroscopic Data 50%
• Cyclopropanation 50%
• X-ray Crystallography 50%
• Sulfur Ylides 50%
• Enones 50%
• Protecting Groups 50%
• Diastereoselectivity 50%
• Stereochemical Assignment 50%
• Tert-Butyldimethylsilyl 50%
• Corey-Chaykovsky Reaction 50%

Chemistry

• Ketones 100%
• Eicosanoid 100%
• Cyclopropane 50%
• X-Ray Crystallography 50%
• Substance Spectroscopy 50%
• Sulfur Ylide 50%
• Enone 50%
• Protecting Groups 50%
• Diastereoselectivity 50%
• Corey-Chaykovsky Ring Formation 50%
• cyclopropanation 50%