A mixed metal phosphate incorporating isonicotinate ligand: Synthesis, crystal structure, and magnetic properties of Cu(HINT)(VO2)(PO 4)

Chih Min Wang; Ya Lan Chuang; Shiuan Ting Chuang; Kwang Hwa Lii

doi:10.1016/j.jssc.2004.02.030

A mixed metal phosphate incorporating isonicotinate ligand: Synthesis, crystal structure, and magnetic properties of Cu(HINT)(VO₂)(PO ₄)

Chih Min Wang, Ya Lan Chuang, Shiuan Ting Chuang, Kwang Hwa Lii

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A mixed metal phosphate incorporating isonicotinate ligand, Cu(HINT)(VO₂)(PO₄), was hydrothermally synthesized and characterized by single-crystal X-ray diffraction and magnetic susceptibility. This compound crystallizes in the monoclinic space group C2/c with cell parameters a=22.033(1)Å, b=6.2986(3)Å, c=16.0202(9)Å, β=121.001(1), and Z=8. The structure consists of two-dimensional neutral sheets of CuVO₂(PO₄) with the dipolar isonicotinate ligand being coordinated to Cu ions as a pendent group. Adjacent sheets are connected by hydrogen bonding. Each sheet consists of infinite chains of CuO₆ octahedra sharing trans edges which are connected by double chains of vanadyl(V) phosphate via corner sharing. Magnetic study results indicate the presence of intrachain ferromagnetic coupling between Cu ions. The magnetic exchange parameter was estimated as 2J/k =51.83K based on an S=1/2 equally spaced ferromagnetic chain model.

Original language	English
Pages (from-to)	2305-2310
Number of pages	6
Journal	Journal of Solid State Chemistry
Volume	177
Issue number	7
DOIs	https://doi.org/10.1016/j.jssc.2004.02.030
State	Published - Jul 2004

Keywords

Copper
Isonicotinate
Phosphate
Vanadium

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10.1016/j.jssc.2004.02.030

CCDC 223134: Experimental Crystal Structure Determination
Lii, K. (Contributor), Wang, C. (Contributor), Chuang, Y. (Contributor) & Chuang, S. (Contributor), The Cambridge Structural Database, 1 Jan 2004
DOI: 10.5517/cc7h5wr, https://doi.org/10.5517%2Fcc7h5wr
Dataset

Cite this

@article{5f18a654cd05415ba6e2fda5e58440e3,

title = "A mixed metal phosphate incorporating isonicotinate ligand: Synthesis, crystal structure, and magnetic properties of Cu(HINT)(VO2)(PO 4)",

abstract = "A mixed metal phosphate incorporating isonicotinate ligand, Cu(HINT)(VO2)(PO4), was hydrothermally synthesized and characterized by single-crystal X-ray diffraction and magnetic susceptibility. This compound crystallizes in the monoclinic space group C2/c with cell parameters a=22.033(1){\AA}, b=6.2986(3){\AA}, c=16.0202(9){\AA}, β=121.001(1), and Z=8. The structure consists of two-dimensional neutral sheets of CuVO2(PO4) with the dipolar isonicotinate ligand being coordinated to Cu ions as a pendent group. Adjacent sheets are connected by hydrogen bonding. Each sheet consists of infinite chains of CuO6 octahedra sharing trans edges which are connected by double chains of vanadyl(V) phosphate via corner sharing. Magnetic study results indicate the presence of intrachain ferromagnetic coupling between Cu ions. The magnetic exchange parameter was estimated as 2J/k =51.83K based on an S=1/2 equally spaced ferromagnetic chain model.",

keywords = "Copper, Isonicotinate, Phosphate, Vanadium",

author = "Wang, {Chih Min} and Chuang, {Ya Lan} and Chuang, {Shiuan Ting} and Lii, {Kwang Hwa}",

note = "Funding Information: We thank the National Science Council for support, Ms. F.-L. Liao and Prof. S.-L. Wang at the National Tsing Hua University for X-ray data collection.",

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TY - JOUR

T1 - A mixed metal phosphate incorporating isonicotinate ligand

T2 - Synthesis, crystal structure, and magnetic properties of Cu(HINT)(VO2)(PO 4)

AU - Wang, Chih Min

AU - Chuang, Ya Lan

AU - Chuang, Shiuan Ting

AU - Lii, Kwang Hwa

N1 - Funding Information: We thank the National Science Council for support, Ms. F.-L. Liao and Prof. S.-L. Wang at the National Tsing Hua University for X-ray data collection.

PY - 2004/7

Y1 - 2004/7

N2 - A mixed metal phosphate incorporating isonicotinate ligand, Cu(HINT)(VO2)(PO4), was hydrothermally synthesized and characterized by single-crystal X-ray diffraction and magnetic susceptibility. This compound crystallizes in the monoclinic space group C2/c with cell parameters a=22.033(1)Å, b=6.2986(3)Å, c=16.0202(9)Å, β=121.001(1), and Z=8. The structure consists of two-dimensional neutral sheets of CuVO2(PO4) with the dipolar isonicotinate ligand being coordinated to Cu ions as a pendent group. Adjacent sheets are connected by hydrogen bonding. Each sheet consists of infinite chains of CuO6 octahedra sharing trans edges which are connected by double chains of vanadyl(V) phosphate via corner sharing. Magnetic study results indicate the presence of intrachain ferromagnetic coupling between Cu ions. The magnetic exchange parameter was estimated as 2J/k =51.83K based on an S=1/2 equally spaced ferromagnetic chain model.

AB - A mixed metal phosphate incorporating isonicotinate ligand, Cu(HINT)(VO2)(PO4), was hydrothermally synthesized and characterized by single-crystal X-ray diffraction and magnetic susceptibility. This compound crystallizes in the monoclinic space group C2/c with cell parameters a=22.033(1)Å, b=6.2986(3)Å, c=16.0202(9)Å, β=121.001(1), and Z=8. The structure consists of two-dimensional neutral sheets of CuVO2(PO4) with the dipolar isonicotinate ligand being coordinated to Cu ions as a pendent group. Adjacent sheets are connected by hydrogen bonding. Each sheet consists of infinite chains of CuO6 octahedra sharing trans edges which are connected by double chains of vanadyl(V) phosphate via corner sharing. Magnetic study results indicate the presence of intrachain ferromagnetic coupling between Cu ions. The magnetic exchange parameter was estimated as 2J/k =51.83K based on an S=1/2 equally spaced ferromagnetic chain model.

KW - Copper

KW - Isonicotinate

KW - Phosphate

KW - Vanadium

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U2 - 10.1016/j.jssc.2004.02.030

DO - 10.1016/j.jssc.2004.02.030

M3 - 期刊論文

AN - SCOPUS:2942679342

VL - 177

SP - 2305

EP - 2310

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

IS - 7

ER -

A mixed metal phosphate incorporating isonicotinate ligand: Synthesis, crystal structure, and magnetic properties of Cu(HINT)(VO2)(PO 4)

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CCDC 223134: Experimental Crystal Structure Determination

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A mixed metal phosphate incorporating isonicotinate ligand: Synthesis, crystal structure, and magnetic properties of Cu(HINT)(VO₂)(PO ₄)