Abstract
The first 26R channel structure, NTHU-5, built up with two types of helical metal phosphite chains has been synthesized under mild hydrothermal conditions; this novel open framework is composed of both octahedral Al3+ and tetrahedral Zn2+ centers and represents the first example with participation of aluminum in a pore size over 20R; the 26R channel is truly a stack of 26-membered rings instead of just an opening; this study has successfully demonstrated that two differently charged metal ions can form M-O-P-O-M′ bonded structure with ring size larger than any other existing inorganic open frameworks; in addition, varied metal analogues can be prepared using the same approach; the system of NTHU-5 has provided an intriguingly new chemical synthesis for inorganic microporous materials with interesting reaction conditions.
Original language | English |
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Pages (from-to) | 5350-5351 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 129 |
Issue number | 17 |
DOIs | |
State | Published - 2 May 2007 |
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CCDC 829334: Experimental Crystal Structure Determination
Lai, Y.-L. (Creator), Lii, K.-H. (Creator) & Wang, S.-L. (Creator), The Cambridge Structural Database, 2012
DOI: 10.5517/ccwtzqc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwtzqc&sid=DataCite
Dataset
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CCDC 829335: Experimental Crystal Structure Determination
Lai, Y.-L. (Creator), Lii, K.-H. (Creator) & Wang, S.-L. (Creator), The Cambridge Structural Database, 2012
DOI: 10.5517/ccwtzrd, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwtzrd&sid=DataCite
Dataset