(2,2-Dimethyl-,a,a,a,′,a′-tetra-phenyl-1,3-dioxolane-4, 5-dimethano-lato-κ2 O 4,O 5)eth-yl(tetra- hydro-furan-O)aluminium(III)

Chien An Chen, Kuo Hui Wu, Han Mou Gau

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Abstract

The title compound, [Al(C2H5)(C31H28O4)(C4H8O)], has a slightly distorted tetra-hedral geometry around the AlIII metal centre. The bidentate TADDOLate ligand and the AlIII metal atom form a seven-membered ring, with an O - Al - O angle of 111.19 (10)°, which is close to the ideal tetra-hedral angle. The Al - O - C(alkoxide) angles of 139.17 (17) and 137.95 (17)° are larger than the sp 3 bond angle, suggesting substantial π-donation of the alkoxide O atom to the AlIII metal centre.

Original languageEnglish
Pages (from-to)m2665-m2666
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number11
DOIs
StatePublished - 5 Oct 2007

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