含過渡金屬中心雜環結構之中間相材料

This two-year proposal continues our original research in generating metallomesogenic materials derived from five- and six-membered heterocycles. This research is to propose a strategic approach for the formation of novel metallomesogens with superstructures, which are expected to exhibit liquid crystalline behavior, magnetic and related electro-optical properties. These materials are associated with unique molecular assemblies in which metal centers as core group have geometries of square plane or pyramid with a coordination number of 4 and 5. Five different types of heterocyclic structures are applied to generate the metallomesogenic materials;